if line begins with backslash in .txt file, do this

I am trying to get an if statement to work in bash that deals with lines beginning with \ in a text file.

Something like this:

shasum -a 256 file_A\\\\\/\/.txt >> file_B.txt
if line begins with '\' in file_B.txt
    then awk '{ print "^.65  ", $0, "$" }' that line in file_C.txt
else
    if line not begin with '\' in file_B.txt
        then awk '{ print "^.64  ", $0, "$" }' that line in file_C.txt
    fi
fi

Contents of file_B.txt:

e5fba57b49dbe8196ee4fb4ddb407885582f88d8e52dfa6e5adb55204b589a88  /Users/1337/file_D.txt
\66590f18dafff57160770d885b090d54455e0fc900342d7752dc420405ae50f5  /Users/1337/file_A\\::.txt

Contents of file_C.txt:

/Users/1337/file_D.txt
/Users/1337/file_A\\::.txt

So, basically, the end result would look like this (this is inside file_C.txt):

^.64  /Users/1337/file_D.txt$
^.65  /Users/1337/file_A\\::.txt$

because line 2 began with a \ and line 1 didn't.

If any of this is confusing, please don't hesitate asking me to clarify.

Mac OS X Yosemite, bash 3.2.57(1)-release