Why does "break" behave like it does in the following piece of code?

count = 1
i = 3
while count != 1000:
     for k in range(2,i):
          if i%k == 0:       
              break
     else:
          print(i)
          count += 1
     i += 2        

In this piece of python code, if "break" is executed the program will jump over to adding i+=2, is it not supposed to execute "else" first?, given that "else" is not indented to the same level of "if" and thus does not make part of the "for" loop.