Series of if statements applied to data frame

I have a question on how to this task. I want to return or group a series of numbers in my data frame, the numbers are from the column 'PD' which ranges from .001 to 1. What I want to do is to group those that are .91>'PD'>.9 to .91 (or return a value of .91), .92>'PD'>=.91 to .92, ..., 1>='PD' >=.99 to 1. onto a column named 'Grouping'. What I have been doing is manually doing each if statement then merging it with the base data frame. Can anyone please help me with a more efficient way of doing this? Still on the early stages of using python. Sorry if the question seems to be easy. Thank you for answering and for your time.